Trick to Draw Lewis Dot Structure | Calculation of Formal Charge | Chemistry Class 11, NEET JEE

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I am going to teach you all about Easy Trick to Draw Lewis Dot Structure and Calculation of Formal charge
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Lewis Symbols: In the formation of a molecule, only the outer shell electrons take part in chemical combination and they are known as valence electrons. The inner shell electrons are well protected and are generally not involved in the combination process.

Kössel and Lewis in 1916 developed an important theory of chemical combination between atoms known as the electronic theory of chemical bonding. According to this, atoms can combine either by transfer of valence electrons from one atom to another (gaining or losing) or by sharing valence electrons in order to have an octet in their valence shells. This is known as the octet rule.

The Lewis dot structures provide a picture of bonding in molecules and ions in terms of the shared pairs of electrons and the octet rule.

The Lewis dot
structures can be written by adopting the
following steps:

• The total number of electrons required for writing the structures is obtained by adding the valence electrons of the combining atoms. For example, in the CH4 molecule there are eight valence electrons available for bonding (4 from carbon and 4 from the four hydrogen atoms).

• For anions, each negative charge would mean the addition of one electron. For cations, each positive charge would result in the subtraction of one electron from the total number of valence electrons. For example, for the CO32– ion, the two negative charges indicate that there are two additional electrons than those provided by the neutral atoms. For NH +4 ion, one positive charge indicates the loss of one electron from the group of neutral atoms.

• Knowing the chemical symbols of the combining atoms and having knowledge of the skeletal structure of the compound (known or guessed intelligently), it is easy to distribute the total number of electrons as bonding shared pairs between the atoms in proportion to the total bonds.

• In general the least electronegative atom occupies the central position in the molecule/ion. For example in the NF3 and CO32–, nitrogen and carbon are the central atoms whereas fluorine and oxygen occupy the terminal positions.

• After accounting for the shared pairs of electrons for single bonds, the remaining electron pairs are either utilized for multiple bonding or remain as the lone pairs. The basic requirement being that each bonded atom gets an octet of electrons.

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