13.2 Effect of ligands on splitting of d-orbitals in transition metal complexes [HL IB Chemistry]
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Ligands split the d orbitals
Ligands split the d orbitals found in the transition metal ion in the complex. Different ligands split the d orbitals differently. A partially filled d orbital will absorb certain frequencies of light, leaving the complex itself to appear the complimentary colour of the light absorbed. Electron(s) promoted to a higher energy d orbital are responsible for the specific wavelengths of light absorbed.
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